Wednesday, August 21, 2019
6 Main Characteristics Of Communication Essay Example for Free
6 Main Characteristics Of Communication Essay (1) Two or More Persons: The first important characteristic of communication is that there must be a minimum number of two persons because no single individual can have an exchange of ideas with himself. A listener is necessary to receive oneââ¬â¢s ideas. Therefore, there must be at least two persons-the sender of information and the receiver. (2) Exchange of Ideas: Communication cannot be thought of in the absence of exchange of ideas. In order to complete the process of communication there must be an exchange of ideas, orders, feelings, etc. , among two or more than two persons. (3) Mutual Understanding: Mutual understanding means that the receiver should receive the information in the same spirit with which it is being given. In the process of communication, it is more important to understand the information rather than carry it out. See more: The stages of consumer buying decision process essay (4) Direct and Indirect Communication: It is not necessary in communication that the receiver and giver of information should be face-to-face with each other. Communication can be both direct and indirect. Direct communication means face-to-face conversation, while indirect communication is through other means. (5) Continuous Process: Communication is an endless process, as is the case with business where the manager continuously assigns work to his subordinates, tries to know the progress of the work and gives directions. (6) Use of Words as well as Symbols: There can be many means of communication, like the written, the oral and symbolic. The examples of symbolic communication are the ringing of bell for closing a school or a college, saying something by the movement of the neck,à showing anger or disapproval through eyes, giving some decision by the raising of a finger in cricket, etc.
Tuesday, August 20, 2019
The Structure And Properties Of Surfactants
The Structure And Properties Of Surfactants Surfactants are compounds that lower the surface tension of a liquid, allowing easier spreading, and lowering of the interfacial tension between two liquids, or between a liquid and a solid. Surfactants may act as: Detergents Wetting agents Emulsifiers Foaming agents Dispersants STRUCTURE OF SURFACTANT Figure 1Surfactant molecule possess a dualistic character.This arises from the combination of a hydrophobic (water-rejecting) and a hydrophilic (water-preferring) group in one molecule.In a classical surfactant,the hydrophobic part usually consists of one or more hydrocarbon chains sometimes with various degrees of unsaturation and branching.However,the apolar part may also be partly or completely fluorinated or may be composed of a siloxane chain.The size and length of the hydrocarbon may vary considerably,but it must consists of atleast 8 carbon atoms.For the hydrophilic part(usually called the headgroup),there is a wide range of possible structures(Table1.1).The hydrophilic part can either be ionic or dipolar depending on whether the headgroup has a net charge or not. [1] PROPERTIES OF SURFACTANTS They enable the cleaning solution to fully wet the surface being cleaned so that dirt can be readily loosened and removed. They clean greasy, oily, particulate-, protein-, and carbohydrate-based stains. They are instrumental in removing dirt and in keeping them emulsified, suspended, and dispersed so they dont settle back onto the surface being cleaned. Surfactants are one of the major components of cleaning products and can be regarded as the workhorses: they do the basic work of breaking up stains and keeping the dirt in the water solution to prevent re-deposition of the dirt onto the surface from which it has just been removed. Surfactants disperse dirt that normally does not dissolve in water. As anyone who uses oil based dressings in the kitchen knows, oil and water do not mix unless shaken vigorously in the bottle. They separate almost immediately afterwards. The same is true when washing your dishes or clothes. With the addition of surfactants, oil, which normally does not dissolve in water, becomes dispersible and can be removed with the wash water. . CLASSIFICATION OF SURFACTANTS It is generally classified in 4 basic types depending upon the nature of the head group: Anionic Non anionic Cationic Amphoteric or zwitter-ionic Anionic Surfactants In solution, the head is negatively charged. This is the most widely used type of surfactant for laundering, dishwashing liquids and shampoos because of its excellent cleaning properties and high sudsing potential. The surfactant is particularly good at keeping the dirt away from fabrics, and removing residues of fabric softener from fabrics. Anionic surfactants are particularly effective at oily soil cleaning and oil/clay soil suspension. Still, they can react in the wash water with the positively charged water hardness ions (calcium and magnesium), which can lead to partial deactivation. The more calcium and magnesium molecules in the water, the more the anionic surfactant system suffers from deactivation. To prevent this, the anionic surfactants need help from other ingredients such as builders (Ca/Mg sequestrants) and more detergent should be dosed in hard water. The most commonly used anionic surfactants are alkyl sulphates, alkyl ethoxylate sulphates and soaps. Non anionic Surfactants These surfactants do not have an electrical charge, which makes them resistant to water hardness deactivation. They are excellent grease removers that are used in laundry products, household cleaners and hand dishwashing liquids. Most laundry detergents contain both non-ionic and anionic surfactants as they complement each others cleaning action. Non-ionic surfactants contribute to making the surfactant system less hardness sensitive. The most commonly used non-ionic surfactants are ethers of fatty alcohols Cationic Surfactants In solution, the head is positively charged. There are 3 different categories of cationics each with their specific application: In fabric softeners and in detergents with built-in fabric softener, cationic surfactants provide softness. Their main use in laundry products is in rinse added fabric softeners, such as esterquats, one of the most widely used cationic surfactants in rinse added fabric softeners. An example of cationic surfactants is the esterquat. In laundry detergents, cationic surfactants (positive charge) improve the packing of anionic surfactant molecules (negative charge) at the stain/water interface. This helps to reduce the dirtl/water interfacial tension in a very efficient way, leading to a more robust dirt removal system. They are especially efficient at removing greasy stains. An example of a cationic surfactant used in this category is the mono alkyl quaternary system. In household and bathroom cleaners, cationic surfactants contribute to the disinfecting/sanitizing properties. Amphoteric Surfactants These surfactants are very mild, making them particularly suited for use in personal care and household cleaning products. They can be anionic (negatively charged), cationic (positively charged) or non-ionic (no charge) in solution, depending on the acidity or pH of the water. They are compatible with all other classes of surfactants and are soluble and effective in the presence of high concentrations of electrolytes, acids and alkalis. These surfactants may contain two charged groups of different sign. Whereas the positive charge is almost always ammonium, the source of the negative charge may vary (carboxylate, sulphate, sulphonate). These surfactants have excellent dermatological properties. They are frequently used in shampoos and other cosmetic products, and also in hand dishwashing liquids because of their high foaming properties. An example of an amphoteric/zwitterionic surfactant is alkyl betaine. Figure 2 Figure 3 SURFACE TENSION Water has many unusual properties as a result of its ability to hydrogen bond. For example, the density of ice is less than that of the liquid and the predicted boiling point is almost 200 degrees C higher than it would be without hydrogen bonding. The water molecules at the surface of water are surrounded partially by air and partially by water. These surface molecules would be much more stable if they could be in the interior of the liquid where all their hydrogen bonds could be fulfilled (cohesion). Therefore, water normally tends to have the smallest surface possible, i.e. it has a high surface tension, in order to achieve the lowest possible energetic state. If a solid material more dense than water is placed on the surface of water, what happens next depends on the nature of the material. If the material is hydrophilic (water loving) it has a surface to which water is attracted. The adhesion of water to the surface of this material coats the surface of the object with water, reduces the surface tension, and causes the object to sink. If the solid object is hydrophobic (water fearing),the unfavorable interactions between the water surface and the object make it difficult to wet the surface. Two forces now come into play the energy it would take to overcome this repulsion and the force of gravity. If the force of gravity is strong enough, it will prevail and the object will sink (assuming that the object has a density greater than water). If the gravitational force is less than the surface tension then the object will float on the surface of the water. Surface tension is what permits water striders and other insects to walk across the surface of water and what enables a needle to float. Of course, the critical feature here is the amount of force per unit area put a needle into water end-on instead sideways and the needle will immediately sink. SURFACTANT FUNCTION Surfactants are also referred to as wetting agents and foamers. Surfactants lower the surface tension of the medium in which it is dissolved. By lowering this interfacial tension between two media or interfaces (e.g. air/water, water/stain, stain/fabric) the surfactant plays a key role in the removal and suspension of dirt. The lower surface tension of the water makes it easier to lift dirt and grease off of dirty dishes, clothes and other surfaces, and help to keep them suspended in the dirty water. The water-loving or hydrophilic head remains in the water and it pulls the stains towards the water, away from the fabric. The surfactant molecules surround the stain particles, break them up and force them away from the surface of the fabric. They then suspend the stain particles in the wash water to remove them. Surfactants can work in three different ways: roll-up, emulsification, and solubilization. Roll-up mechanism The surfactant lowers the oil/solution and fabric/solution interfacial tensions and in this way lifts the stain of the fabric. Figure 3 Emulsification The surfactant lowers the oil-solution interfacial tension and makes easy emulsification of the oily soils possible. Figure 4 Solubilization Through interaction with the micelles of a surfactant in a solvent (water), a substance spontaneously dissolves to form a stable and clear solution How can surfactants prevent dirt from being re-deposited? Surfactants have a vital role to play in preventing the re-deposition of soils like greasy, oily stains and particulate dirt on the surface or fabric from which they have just been removed. This works by electrostatic interactions and steric hindrance. Electrostatic interactions Anionic surfactants are adsorbed on both the surface of the dirt which is dispersed in the detergent solution, and the fabric surface. This creates a negative charge on both surfaces, causing electrostatic repulsions. This repulsion prevents the soil from re-depositing on the fabric. In the presence of hardness, however, this mechanism acts like a bridge between the suspended soil and the fabric. This is another reason why hardness sequestrants (a chemical that promotes Ca/Mg sequestration) are often used in detergents. Steric hindrance: Non-ionic surfactants like alcohol ethoxylates also adsorb on the dirt. Their long ethoxylated chains extend in the water phase and prevent the dirt droplets or particles from uniting and from depositing onto the fabric surface.Dirt is present in solution. The non-ionic surfactants adsorb to the dirt particles.Their long hydrophilic heads extend in the water phase and as a result prevent the dirt particles/droplets from uniting and from re-depositing onto fabrics. [2] SURFACTANT USES There are many uses of surfactant in different industries and different fields. Some of them are discussed below: Use of Surfactant in Detergents Surfactants are literally Surface Acting Agents. They are called this because they act to reduce the surface tension of a liquid, especially water. They are large molecules with two distinct parts. First there is a head which is hydrophilic. This means that it is attracted to water and soluble in water, usually because it has a positive or negative charge. The other part of the surfactant is the tail which is hydrophobic, meaning it is repelled by water. The tail is also lipophilic which means that it is soluble in organic solvents particularly oils and fats or lipids. It is this mixed structure which gives a surfactant its properties. When added to water the surface tension of water is reduced. The surface tension of water is caused by the hydrogen bonds which form between the slight charges on different parts of the water molecule (for further information see the water article). Surfactants break up these hydrogen bonds by remaining at the surface, their heads dissolved in the water but their tails extending out of the water, repelled by it. When the surfactant concentration increases sufficiently, micelles are formed. These are spheres of surfactant with all the heads on the outside protecting all the tails within.[3] Use of Surfactant in Cosmetics Shampoos and soaps clean by the use of surfactants (surface active agents). Surfactant molecules have both fat soluble (lipophilic) and water-soluble (hydrophylic) parts. The lipophilic part of the molecule sticks to oil and dirt, and the hydrophilic part allows water to then carry away the otherwise water-insoluble grime. Washing-up detergents work in the same way, although it isnt generally advisable to wash your hair with dishwashing liquid they are formulated to remove thick grease from plates, not to gently clean your hair! [4] Use of Surfactants to remove solvent-based inks from plastic films There is substantial economic and environmental incentive to remove the ink (deink) from heavily printed plastic films so that the plastic can be reused to produce clear films. In this study, polyethylene films printed with solvent-based ink were deinked using surfactants under a variety of conditions. Water without surfactant does not deink the solvent-based ink from plastic films over a pH range of 3 to 12. In common with earlier studies of water-based inks, it is found that solutions of cationic surfactants are the most effective for deinking of solvent-based ink but a pH of at least 11 is required. Presoaking of plastic film in aqueous solution of cationic surfactant increases the level of deinking. Limited studies performed with a pilot-size paper deinking apparatus on solvent-based ink removal indicates that the deinking of plastic film using surfactant solutions is technically feasible. [5] Pulmonary Surfactants and Therapeutic uses, including Pulmonary Lavage The present invention discloses useful surfactant molecules including polypeptides, proteins, and a variety of other organic molecules, as well as methods of making and using same. Surfactant compositions, including liposomal surfactant compositions, are also disclosed. Use of the surfactant molecules of the present invention in pulmonary lavage procedures for a variety of therapeutic applications is also disclosed, including the treatment of respiratory distress syndrome; the removal of inflammatory exudate from inflamed lung tissues; and the treament of meconium aspiration syndrome in infants. [6] Adsorption of non-petroleum base Surfactant on reservoir rock SURFACTANT molecules adsorb well to solid interfaces such as the porous media found in petroleum reservoirs.The adsorbed surfactant layer represents both an additional resistance to flow as well as loss of surfactant properties and is therefore, of fundamental importance in the enhanced oil recovery (EOR) process that involves the flow of surfactant solution through porous media.According to Austad and Milter1, chemical flooding of oil reservoirs is one of the most successful methods to enhance oil recovery from depleted reservoirs at low pressure. [7] Use of Surfactant in Neonates Surfactant replacement therapy has become an established treatment for neonatal respiratory distress syndrome (RDS). This article reviews the current evidence for the various practices regarding the use of surfactant in this condition, looking at surfactant type, timing of the first dose, size and frequency of the dose and the need for further doses. As the use of surfactant is expanding into other lung diseases in adults as well as children, we also review those neonatal conditions where surfactant may be of benefit and summarize the evidence published to date supporting its use in these conditions. [8] Surfactant as Antifog Many of the cheaper anti-fogs are made of surfactants like glycerin (soap) and water or alcohol combinations. That works for a very short period. Better anti-fogs usually contain advanced silicones but suffer from poor spreading. You have to rub them in and wipe off excess. [9] Surfactant as Fabric Softner Fabric softeners have long been used to soften fabric and prevent static cling. Available in dryer sheets or liquid form, fabric softeners are made up of surfactants or surface acting agents. It is these chemicals that create a softer, fluffier feel to your laundry. Surfactants contain chemicals with lubricating properties. These chemicals coat fabrics with a waxy film that lubricates them, causing them to feel smoother or fluffier. Its suggested that these lubricating chemicals also make ironing easier and reduce drying time and wrinkling. The lubricating properties of surfactants are a result of positive charges affecting negative charges. Surfactants are generally acidic and made up of positively charged particles. These positively charged particles attract the negatively charged particles within scratchy fabric. The negative charge is neutralized, creating a lower frictional resistance. Thus, there is less static cling and the fabric feels softer and less scratchy to touch. [10] Surfactant in Ski Waxes Once the ski is in motion, you are applying pressure and exerting friction, melting the snow, and creating a fine layer of water between your ski base and the snow. Control and maneuverability in skiing is derived from altering the structure of this water. Hertel wax systems perform a special process using an encapsulation process; tiny bits of surface-active agents formulated into the waxes interact with water, decreasing surface tension and friction, plus increasing control. The wax breaks up the water (snow) resulting in easier running, better control, added safety, and more fun. When commanded to turn, skis slide with ease. [11] Effect of oil soluble Surfactant in emulsions stabilised by clay particles Although surfactants and particles are often mixed together in emulsions, the contribution of each species to the stabilisation of the oil-water interface is poorly understood. We report the results of investigations into the formation of emulsions from solutions of surfactant in oil and aqueous suspensions of laponite. Depending on the salt concentration in the aqueous suspensions, the laponite dispersed as individual disc-shaped particles, 30 nm in diameter, or flocculated into aggregates tens of micrometres in diameter. At the concentrations studied, the flocculated particles alone stabilized oil-in-water emulsions. Synergistic interactions between the particles and octadecylamine at the oil-water interface reduced the average emulsion drop size, while antagonistic interactions with octadecanoic acid enhanced coalescence processes in the emulsions. The state of particle dispersion had dramatic effects on the emulsions formed. Measurements of the oil-water interfacial tension revea led the origins of the interactions between the surfactants and particles. [12] Surfactant in process for deinking of recycled paper A process for deinking recycled paper using a pressurized deinking module to separate ink from paper pulp stock. The addition of salts of imidazolinium based compounds with alkyl, alkenyl and amidoethyl side chains to the pulp slurry at the beginning of the pressurized deinking module cycle removes ink more effectively and results in a brighter recycled paper and an increase in yield of final paper stock. [13] Surfactant in Spermicides (NONOCYNOL-9) The most common active ingredient of spermicides is Nonoxynol 9. Spermicides containing Nonoxynol-9 are available in many forms, such as jelly (gel), films, and foams. Nonoxynol-9, sometimes abbreviated as N-9, is an organic compound that is used as a surfactant. It is a member of the nonoxynol family of nonionic surfactants. N-9 and related compounds are ingredients in various cleaning and cosmetic products. Its use is controversial because it may cause genital lesions. Nonoxynol-9s ability to kill microbes in vitro was initially taken as evidence that it might be effective at preventing STD transmission. However, more recent findings indicate that it may actually increase a persons risk of contracting STDs, especially if used frequently. This is because the chemical causes tiny abrasions inside the sensitive vaginal and anal walls. [14] Surfactant in Ferro Fluid:Magnetic Liquid Technology A ferrofluid is a stable colloidal suspension of sub-domain magnetic particles in a liquid carrier. The particles, which have an average size of about 100Ã⦠(10 nm), are coated with a stabilizing dispersing agent (surfactant) which prevents particle agglomeration even when a strong magnetic field gradient is applied to the ferrofluid. The surfactant must be matched to the carrier type and must overcome the attractive van der Waals and magnetic forces between the particles. The colloid and thermal stabilities, crucial to many applications, are greatly influenced by the choice of the surfactant. A typical ferrofluid may contain by volume 5% magnetic solid, 10% surfactant and 85% carrier. [15] Surfactant as Alkali Surfactant Polymers In the Alkaline Surfactant Polymer (ASP) process, a very low concentration of the surfactant is used to achieve ultra low interfacial tension between the trapped oil and the injection fluid/formation water. The ultra low interfacial tension also allows the alkali present in the injection fluid to penetrate deeply into the formation and contact the trapped oil globules. The alkali then reacts with the acidic components in the crude oil to form additional surfactant in-situ, thus, continuously providing ultra low interfacial tension and freeing the trapped oil. In the ASP Process, polymer is used to increase the viscosity of the injection fluid, to minimize channeling, and provide mobility control. Oil Chem Technologiess patented ORS and ORS-HF series surfactants are specifically formulated for each field to optimize the oil recovery. Crude oil characteristics, brine characteristics, bottom hole temperature, alkali, well history, and treatment design are considered to maximize the treatment results. [16] Other applications of surfactants are: In biochemistry, the practical as well as theoretical importance of surfactants may be illustrated with the following examples: Surfactants have allowed the investigation of molecular properties of membrane proteins and lipoproteins, acting as solubilizing agents and as probes for hydrophobic binding sites. The properties of surfactants, as well as further facts relevant to the particular experiments, must be carefully considered. Surfactants have successfully contributed to the purification of receptors in their active forms, such as the neuropeptide receptors and opiate receptors. All holoreceptor- complex and reaction- center isolations require the use of a surfactant in order to separate the integral protein systems from the rest of the membrane. Surfactants have been used in the investigation of the denaturation of bacteriorhodopsin and in thermal stability experiments of rhodopsin. The operations of exchange and removal of surfactants bound to membrane proteins are crucial and have been successfully applied to a wide variety of these proteins. The effects of surfactants on the function of membrane-bound enzymes such as cytochrome P-450 and (Na+ + K+)-ATPase have also been determined. Integral membrane proteins can be separated from hydrophilic proteins and identified as such in crude surfactant extracts of membrane or cells . Methods for the solubilization of low-density lipoproteins have advanced the understanding of the assembly, interconversion and molecular exchange processes with plasma lipoproteins. In electrophoresis, various techniques require the use of surfactants. The popular techniques of SDS-PAGE for the identification and subunit molecular weight estimation of proteins is based on a specific type of surfactant-protein interaction. 2D-PAGE uses SDS in one direction and Triton X-100 in the other. This technique has been used to identify proteins containing long hydrophobic regions and relies on the different binding ability of non-ionic surfactants to water-soluble and intrinsic membrane proteins. Isoelectric focusing, native electrophoresis and blotting are other electrophoretic techniques which may need surfactants for the solubilization or transfer of membrane proteins. In high performance liquid chromatography, common techniques such as ion-exchange HPLC, reversed-phase HPLC and sizeexclusion-HPLC may require surfactants to solubilize membrane proteins. Ionpair HPLC requires surfactants as reagents in order to achieve the separation conditions (ionpairing). Affinity surfactants have been used as reversibly bound ligands in high performance affinity chromatography. Crystallization of membrane proteins was achieved using short chain surfactants, which are believed to shield the hydrophobic intermembrane part of the molecule. Thus the polar interactions betvveen individual molecules come into play, providing the stabilizing force in crystallization. Surfactants are also employed to promote the dissociation of proteins from nucleic acids on extraction from biological material. Further applications of surfactants in biochemistry are the solubilization of enzymes in apolar solvents via reversed micelles and the isolation of hydrophobic proteins. [17] CAPTION TO FIGURES: Figure 1-http://www.scienceinthebox.com/en_UK/glossary/popup-roll-up-mechanism.html Figure 2-http://www.scienceinthebox.com/en_UK/glossary/popup-emulsification.html Figure 3-http://www.caes.uga.edu/applications/publications/files/html/B1319/images/Figure%202.jpg BOOK REFERREDFigure 4-http://www.inkline.gr/inkjet/newtech/tech/dispersion/surfactants.gif APPLIED SURFACTANTS:PRINCIPLES AND APPLICATIONS -BY THARWAT F. TADROS WILEY-WCH PUBLICATION
My Agony is More Noble Than Your Pain :: Essays Papers
My Agony is More Noble Than Your Pain In a world where an infallibly righteous God oversees justice, the source of all human suffering is known and understood. While this may not make the pain of the punishment He assigns any less agonizing, it at least lends it clarity. When Job loses his family and his fortune, he immediately knows with whom to take up his case. However, in a world where the gods do not determine all human actions and exert their influence arbitrarily, oneââ¬â¢s misfortune is wholly oneââ¬â¢s own to bear, no matter how undeserved it may be. Sophocles emphasizes this human aspect of injustice in Electra and Philoctetes, placing both main characters in a position of undeserved suffering caused largely by human actions. Electra and Philoctetes are in a situation comparable to Jobââ¬âthey were wronged by powers mightier than themselves and bringing those powers to justice is an arduous or downright impossible task. Both characters must decide whether to cling to their suffering because it is just , at the expense of their humanity or their lives, or to relinquish it in order to rejoin society either literally, in Philoctetesââ¬â¢s case, or metaphorically in Electraââ¬â¢s. Where Job could not feasibly punish God, and was therefore left with only the choice between abandoning or maintaining his faith in the face of injustice, the world of arbitrary and human injustice opens a new avenue to end suffering: revenge. Electra immediately seizes on this as her only hope of salvation and sets the machinery to accomplish it in motion by sending Orestes off with Pedagogus after her fatherââ¬â¢s murder. However, this shifts her control of the revenge out of her hands and, while her communication with Orestes keeps the prospect close enough to obsess her, it also renders her entirely passive to his will. The chorus repeatedly rebukes her for her self-inflicted misery, claiming that nothing will assuage it once it has been too deeply entrenched. They say, ââ¬Å"If past the bounds of sense you dwell in grief that is cureless, with sorrow unending, you will only destroy yourself, in a matter where evil knows no deliveranceâ⬠¦Why do you seek it?â⬠(Electr a, 140-145). Electra does not refute the truth of their speech, focusing instead on her admiration of those who cling to suffering. In contrast, whatever desire for vengeance Philoctetes has towards those who wronged him, he can only direct it through curses and appeals to the gods because he has no reasonable hope of punishing Odysseus and the Atridae himself. My Agony is More Noble Than Your Pain :: Essays Papers My Agony is More Noble Than Your Pain In a world where an infallibly righteous God oversees justice, the source of all human suffering is known and understood. While this may not make the pain of the punishment He assigns any less agonizing, it at least lends it clarity. When Job loses his family and his fortune, he immediately knows with whom to take up his case. However, in a world where the gods do not determine all human actions and exert their influence arbitrarily, oneââ¬â¢s misfortune is wholly oneââ¬â¢s own to bear, no matter how undeserved it may be. Sophocles emphasizes this human aspect of injustice in Electra and Philoctetes, placing both main characters in a position of undeserved suffering caused largely by human actions. Electra and Philoctetes are in a situation comparable to Jobââ¬âthey were wronged by powers mightier than themselves and bringing those powers to justice is an arduous or downright impossible task. Both characters must decide whether to cling to their suffering because it is just , at the expense of their humanity or their lives, or to relinquish it in order to rejoin society either literally, in Philoctetesââ¬â¢s case, or metaphorically in Electraââ¬â¢s. Where Job could not feasibly punish God, and was therefore left with only the choice between abandoning or maintaining his faith in the face of injustice, the world of arbitrary and human injustice opens a new avenue to end suffering: revenge. Electra immediately seizes on this as her only hope of salvation and sets the machinery to accomplish it in motion by sending Orestes off with Pedagogus after her fatherââ¬â¢s murder. However, this shifts her control of the revenge out of her hands and, while her communication with Orestes keeps the prospect close enough to obsess her, it also renders her entirely passive to his will. The chorus repeatedly rebukes her for her self-inflicted misery, claiming that nothing will assuage it once it has been too deeply entrenched. They say, ââ¬Å"If past the bounds of sense you dwell in grief that is cureless, with sorrow unending, you will only destroy yourself, in a matter where evil knows no deliveranceâ⬠¦Why do you seek it?â⬠(Electr a, 140-145). Electra does not refute the truth of their speech, focusing instead on her admiration of those who cling to suffering. In contrast, whatever desire for vengeance Philoctetes has towards those who wronged him, he can only direct it through curses and appeals to the gods because he has no reasonable hope of punishing Odysseus and the Atridae himself.
Monday, August 19, 2019
Critical Analysis on The Scream by Edvard Munch Essay example -- a cri
Critical Analysis on The Scream by Edvard Munch Edvard Munch was born on December 12 1863 in Loten Norway. He moved to Christiana, and spent most of his childhood there. Both his mother and his oldest sister suffered from tuberculosis and died before he reached the age of 14. At 18 he became more serious about his art and started attending art school. Edvard finally found a release for the pain he felt from his sisterââ¬â¢s death. In 1886 he painted ââ¬Å"The Sick Childâ⬠. The painting was so emotionally charged that it received a lot of criticism from the press and the public. However some of his artist colleagues began to recognize his talent. The same year another tragedy struck. His father died in November. Edvard received some scholarships that allowed him to spend the next few years in Paris. Although he would return to Norway during the summer, his style was that of a French Impressionist. In 1892 Munch submitted a series of paintings into a major Berlin art show. His exhibit was titled ââ¬Å"The Frieze of Lifeâ⬠. This show caused an even larger uproar than his previous work. Edvard became a celebrity overnight and he painted such paintings as ââ¬Å"the sick childâ⬠ââ¬Å"the screamâ⬠and ââ¬Å"vampireâ⬠, which showed his true emotion feelings. Edvard Munch had been through a lot of trauma, hurt and heartbreak in his life and his art work and painting helped him to expressive his feelings. I am going to be analysing and studing the Painting ââ¬Å"The Screamâ⬠. Edvard Munch was an Impressionist painter. Expressionism is movement in the arts during the early part of the 20th century that emphasized subjective expression of the artist's inner experiences. This may ... ...e of the loneliest, scariest, and the most amazing place were we can escape to, and were no one else can know what you are thinking. I have seen how to symbolise certain things by colours and shapes and how to give a certain impression and mood. I can see how amazing dreams and nightmares are because they are not in this world, but they are only true portraits our ourselves and our lives so anything is possible and even our darkest and saddest feelings that we bury away inside us can show and come to life in our dreams. I have learnt to make a straightforward piece of art turn into an emotional and deep feeling that every person has different views and feeling about depending on their own lives. I can now see how this piece of artwork is truly individual, remarkable and unique as it shows that emotions of a broken man.
Sunday, August 18, 2019
Michèle Robertsââ¬â¢s The Looking Glass Essay -- Michele Roberts Looking G
Michà ¨le Robertsââ¬â¢s The Looking Glass The understanding of history as a linear and unproblematic narrative, dominated by kings and queens, warriors and heroes, has long been denied by women writers. As Linda Anderson argues, these events ââ¬Ëtake on a different meaning, a different configuration when we begin to see through them ââ¬â in both senses ââ¬â to womenââ¬â¢s concealed existence in the private sphere of family and homeââ¬â¢ (Anderson, p.130). Women have little place in traditional linear history and have come to deny its authority and question its dominance. Frieda Johles Forman, in her introduction to a 1989 collection of essays on womenââ¬â¢s temporality, argues that women suffer from a lack of history, an unrecorded past, and that this ââ¬Ëabsence strikes at odd, unsuspecting momentsââ¬â¢ (Forman, p.8). But this absence of history is changing, as women begin to write their own stories and their own conceptions of the past. Womenââ¬â¢s time and the political implications for femini sm of feminist historiography have spawned a wealth of writing in recent years. Even in the academic world of history, reliance upon major events as the narrative of history has been undermined by the possibility of a narrative of everyday lives, of everyday events and occurrences.1 However, this re-recording and re-making of history is fraught with danger, as Anderson warns: The ââ¬Ëreclaiming of historyââ¬â¢, the discovery of how our foremothers preceded and even anticipated us, can help to assure us that, despite the evidence, we do in fact exist in the world; yet if we ignore how that existence is textually mediated we end up simply reconstituting ââ¬Ërealityââ¬â¢ as it is. (p.134) Anderson argues that, despite the development of a critique of historyââ¬â¢s claim to objectivity a... ... and Sowton, Caoran, eds., Taking Our Time: Feminist Perspectives on Temporality (Oxford: Pergamon, 1989) Heath, Stephen, Flaubert: Madame Bovary (Cambridge: Cambridge University Press, 1992) Irigaray, Luce, Sexes and Genealogies, trans. Gill, Gillian C. (New York: Cornell University Press, 1993) Michaud, Guy, Mallarmà ©, trans. Collins, Marie and Humez, Bertha (London: Peter Owen, 1966) Millan, Gordon, Mallarmà ©: A Throw of the Dice (London: Secker and Warburg, 1994) Oliver, Hermia, Flaubert and an English Governess (Oxford: Clarendon, 1980) Pearson, Roger, Unfolding Mallarmà ©: The Development of a Poetic Art (Oxford: Clarendon, 1996) Roberts, Michà ¨le, The Looking Glass (London: Little Brown, 2000) Spencer, Philip, Flaubert: A Biography (London: Faber and Faber, 1951) Steegmuller, Francis, Flaubert and Madame Bovary (London: Constable, 1993.
Saturday, August 17, 2019
Data Collection Plan Essay
Abstract Postoperative Pulmonary complications (PPC) such as atelectasis, impaired gas exchange, pneumonia and acute respiratory failure (ARF) are not uncommon in patients undergoing major surgery and are a leading cause of increased patient morbidity, mortality and increased length of hospital stay (Yoder, Sharma, Hollingsworth, Talavera, & Rice, 2013). Healthcare professionals are now expected to give patients verifiably effective treatments by implementing current evidence based practice (EBP). In order to do so, interventions to prevent PPCs must be investigated. The aim of this study was to evaluate the effectiveness of adding incentive spirometry (IS) to traditional postoperative chest physiotherapy (CPT) and respiratory care. Eighty patients between 30 and 50 year old who had undergone surgery participated in the study. Patients were divided into two groups: the intervention group where IS was used in addition to the traditional CPT, and the control group which included only traditiona l CPT. The results obtained in the investigation indicated that there were significant differences between both groups at the end of the study in terms of PPCs and hospital length of stay (LOS). Conclusion: Addition of IS to postoperative care helped in controlling PPCs. Keywords: postoperative pulmonary complication, incentive spirometer, chest physiotherapy, length of Stay Research Question In postsurgical patients, how does using incentive spirometer, compared to not using incentive spirometer, affect incidence of PPCs and hospital LOS? Hypothesis Because the risk for developing PPCs is not well studied specific numbers of occurrences are difficult to predict. However, it was hypothesized that patients who incorporated IS as part of their postoperative care would have a clinically significant decrease in the occurrence of PPCs and hospital LOS compared to those who did not incorporate IS into their postoperative care. Data Collection A quasi-experimental control trial was conducted from February 1, 2014 to May 31, 2014. The lead researcher, Adrienne Hinson, collected the data personally. During the four month study, eighty patients ranging in age from 30 to 50 years old who were undergoing surgery where the abdomen or chest was opened were selected randomly from the General Surgery Department at McLeod Regional Medical Center in Florence, SC. On sampling days, patients meeting the criteria were numbered chronologically based on their surgery time. For eighty consecutive business days, one of the patients was chosen randomly using a random numbers table created on Microsoft Excel. Patients who had recently been diagnosed with or treated for acute pulmonary complications, those who could not be instructed or supervised to assure appropriate use of the IS, and patients whose cooperation or comprehension was lacking were excluded from the study. All appropriate procedures were used to safeguard the rights of study participants. The study was externally reviewed by the hospitalââ¬â¢s institutional review board before data collection began. Patients received verbal and written explanations of the study purpose and data collection procedures and after indicating willingness to participate in the study, voluntary informed consent was obtained (See Appendix A). Information included within the informed consent included participant status; participants were told which postoperative activities were routine, and which activities were being evaluated. Participants were informed that the data collected about them would be used for research purposes. The overall goals of the research, to evaluate to addition of IS to postoperative care, was described to patients. Participants were informed about which types of data would be collected, what procedures they would undergo, and how they were selected. The time frame of the commitment was defined as beginning on post-op day one and lasting until their follow upà visit after discharge. Information regarding funding was available to participants. All participants were educated on potential risks and benefits of participation. Finally, patients were assured that their privacy would be protected at all times and that they would be allowed to withdraw from the study at any point during their hospital stay (Polit & Beck, 2012). The patients were deliberately placed into one of two experimental groups. Deliberate placement reduces confounding by ensuring the two groups were comparable when age, sex, smoking history, type of surgery and post-operative analgesia were compared. The control group consisted of 40 patients who underwent routine chest physiotherapy (CPT) postoperatively, as recommended by the Clinical Practice Guidelines set forth by The Agency for Healthcare Research Quality (2011). A physiotherapist supervised and assisted the treatment twice a day in the first two postoperative days and once a day from the third to the tenth days. During any session, the patients performed three to five deep breaths interspersed with periods of quiet breathing followed by two or three coughs or huffs with support from a pillow at least 10 times over a 15 minutes period. Additional techniques such as positioning and chest wall percussion were applied if breathing and coughing exercises alone were not effective in clearing excessive or retained pulmonary secretions. Patients were instructed to perform coughing and deep breathing exercises independently every hour while awake. The treatment group consisted of the remaining 40 patients who also followed the same Clinical Practice Guidelines but also received breathing exercise training with IS (Voldyne Volumetric manufactured by Sherwood Medical Company U.S.A.) In addition to the routine chest physiotherapy up to the tenth postoperative day. Application of breathing training with incentive spirometry was applied for five minutes, five times a day (El-Marakby et al., 2013). Monitoring began immediately postoperatively and continued until discharge. Hospital LOS was documented for each patient, along with whether or not the patient developed a PPC within 10 days of surgery. The researcher rounded on each hospitalized patient daily to ensure compliance and to update discharges and PPC diagnoses. In order to determine LOS, participant observation was used as a tool to collect data. LOS was calculated by subtracting day of admission from day of discharge. Date of admission was the date of surgery for all participants. Date of discharge was determinedà by the surgical teams, who were blinded to the study and therefore measures are not likely to be influenced by reactivity (Polit & Beck, 2012). PPCs were defined as any pulmonary abnormality that produced identifiable disease or dysfunction, was clinically significant, and adversely affected the postoperative clinical course (Hayden, Mayer, & Stoller, 1995). Patients were monitored daily for 10 days for the diagnosis of a PPC. Given this definition, PPCs documented included atelectasis, pneumonia, acute respiratory failure, and exacerbation of COPD. Along with physical assessment and past history, biophysiological measures were used as data collection tools to aid in the diagnosis of PPCs (See Appendix C). Equipment and lab analysis were readily available and tests for biophysiological measures were completed by the appropriate staff at McLeod Regional Medical Center. Ordering tests and the interpretation of results was fulfilled solely by the healthcare providers as deemed necessary. The researchers were not responsible for diagnosing PPCs, but rather the observation and recording of data. Biophysiological measures for diagnosing acute respiratory failure include a low level of oxygen; a pulse oximetry falling below 80% saturation on room air or when arterial blood gas shows PaO2.
Friday, August 16, 2019
Consumer Buying Behaviour Towards Branded Milk Essay
Common application form for income schemes UTI ââ¬â Bond Fund UTI ââ¬â Floating Rate Fund STP (An open ended pure debt fund) The product is suitable for investors who are seeking*: l Regular returns for long-term l Investment predominantly in medium to long term debt as well as money market instruments l Low risk (Blue) (An open-ended Income Scheme) The product is suitable for investors who are seeking*: l Regular income over short-term l UTI ââ¬â Credit Opportunities Fund Investment in floating rate debt / money market instruments, fixed rate debt / money market instruments swapped for floatingratereturn Low risk (Blue) (An open-ended Income scheme) The product is suitable for investors who are seeking*: l Reasonable income and capital appreciation over long-term l Investment in debt and money market instruments across different maturities & credit rating l Low risk (Blue) UTI ââ¬â Gilt Advantage Fund LTP (An open-ended Gilt Scheme) The product is suitable for investors who are seeking*: l Long-term credit risk free return l UTI ââ¬â Dynamic Bond Fund (An open ended income scheme) The product is suitable for investors who are seeking*: l Optimal returns with adequate liquidity over medium-term l Investment in debt/ money market instruments l Low risk (Blue) Investment in sovereign securities issued by the Central Government and/ or a State Government and / or any security unconditionally guaranteed by the Central Government and / or a State Government Low risk (Blue) UTI ââ¬â G-SEC STP UTI ââ¬â Fixed Maturity Plan (An close-ended Umbrella Income Scheme comprising of several Investment Plans) The product is suitable for investors who are seeking*: l Regular income for short term l Investment in Debt/Money Market Instrument/ Govt. Securities l Low risk (Blue) 1 (An open-ended dedicated gilt fund) The product is suitable for investors who are seeking*: l Short term credit risk free return . l Investment in Central Government Securities, Treasury Bills, Call Money and Repo Low risk (Blue) Please read overleaf July 1, 2013 UTI ââ¬â Liquid Cash Plan (An open-ended income scheme) The product is suitable for investors who are seeking*: l Steady and reasonable income over shortterm with capital preservation. l Investment in money market securities & high quality debt l Low risk (Blue) UTI ââ¬â Monthly Income Scheme (An open-ended debt oriented scheme) The product is suitable for investors who are seeking*: l Regular income over medium-term l Investment in equity instruments (maximum-15%) and fixed income securities (debt and money market securities) l Medium risk (Yellow) UTI ââ¬â Mahila Unit scheme (An open-ended debt oriented scheme) This product is suitable for investors who are seeking*: l Reasonable income with moderate capital appreciation over a long-term horizon l Investment in equity instrument (maximum-30%) and debt/ money market instruments l Medium risk (Yellow) UTI ââ¬â Short Term Income Fund (An open-ended income scheme) The product is suitable for investors who are seeking*: l Steady and reasonable income over short-term l Investment in money market securities/ high quality debt l Low risk (Blue) UTI ââ¬â MIS-Advantage Plan (An open-ended income scheme) The product is suitable for investors who are seeking*: l Long-term capital appreciation and regular income over medium-term l Investment in equity instruments (maximum-25%) and fixed income securities (debt and money market securities) l Medium risk (Yellow) UTI ââ¬â Treasury Advantage Fund (An open-ended Income Scheme) The product is suitable for investors who are seeking*: l Capital preservation and liquidity for short-term l Investment in quality debt securities/ money market instruments l Low risk (Blue) UTI ââ¬â Money Market Fund (An open-ended Money Market Mutual Fund) The product is suitable for investors who are seeking*: l Current income consistent with preservation of capital over short-term l Investment in short-term money market securities l Low risk (Blue) UTI ââ¬â Unit Scheme for Charitable & Religious Trusts & Registered Societies (UTI-C.R.T.S) (An open-ended income scheme) The product is suitable for investors who are seeking*: l Regular income over long-term l Investment in equity instruments (maximum-30%) and debt/ money market instruments l Medium risk (Yellow) *Investorsshouldconsulttheirfinancialadvisersifindoubtaboutwhethertheproductissuitableforthem. Note: Risk is represented as: (BLUE) Investors understand that their principal will be at low risk (YELLOW) Investors understand that their principal will be at medium risk (BROWN) Investors understand that their principal will be at high risk COMMON APPLICATION FORM FOR INCOME SCHEMES PLEASE FILL IN ALL COLUMNS IN CAPITAL LETTERS ONLY PLEASEUSESEPARATEFORMFOREACHSCHEME Sr.No. 2013/ Registrar Sr. No. (PLEASEREADINSTRUCTIONSCAREFULLYTOHELPUSSERVEYOUBETTER) DISTRIBUTOR INFORMATION (only empanelled Distributors/Brokers will be permitted to distribute Units) (refer instruction ââ¬Ëhââ¬â¢) ARN NameofFinancialAdvisor SubARNCode SubCode/ Bank Branch Code MOCode EUINo. @ UTI RM No. BDA / CA Code ARN ââ¬â 11770 E020436 UpfrontcommissionshallbepaiddirectlybytheinvestortotheAMFI/NISMcertifiedUTIMFregisteredDistributorsbasedontheinvestorsââ¬â¢assessmentofvariousfactorsincludingtheservicerenderedbythedistributor. @I/We confirm that the EUIN box is intentionally left blank by me/us as this is an ââ¬Å"execution-onlyâ⬠transaction without any interaction or advice by the distributor personnel concerned or notwithstanding the advice of in-appropriateness, if any, provided by such distributor personnel and the distributor has not charged any advisory fees for this transaction. 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